Browse Topic: Emissions

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In Situ Observation of Different Soot Layers in a Model Filter Channel During Its Regeneration2025-01-0312To be published on 07/02/2025
To keep the air clean, wall-flow particulate filters are predominantly used in the exhaust gas after-treatment systems of combustion engines to remove reactive soot and inert ash particles. These filters consist of parallel porous channels with alternately closed ends, effectively separating particles by forming a layer on the filter surface. However, the particulate layer increases the pressure drop, requiring periodic regeneration. During regeneration, soot oxidation breaks up the particulate layer, while resuspension and transport of individual agglomerates may occur. These phenomena are influenced by gas temperature and velocity, as well as dispersity and the reactivity of the soot particles. Sustainable fuels can produce different types of soot with different reactivities and dispersities, therefore this study focuses on the influences of soot dispersity and reactivity by varying the reactive particle system. A model wall-flow filter channel is used for the investigation, enabling
Desens, Ole, Hagen, Fabian P., Meyer, Jörg, Dittler, Achim
Technical Paper
Prediction of hazardous gaseous emissions from a gasoline engine during cold starts using machine learning methods2025-01-0321To be published on 07/02/2025
Internal combustion engines generate higher exhaust emissions of hazardous gases during the initial minutes after engine start. Experimental data from a state-of-the-art turbo-charged 3-cylinder, 999 cc gasoline engine are used to predict cold start emissions using two Machine Learning (ML) models: a Multilayer Perceptron (MLP) which is a fully connected neural network and an Encoder-Decoder Recurrent Neural Network (ED-RNN). Engine parameters and various temperatures are used as input for the models and NOx (Nitrogen Oxides), CO (Carbon monoxide) and unburned hydrocarbon (UHC) emissions are predicted. The dataset includes time series recordings from the Worldwide harmonized Light-duty vehicles Test Cycle (WLTC) and four Real Diving Emissions (RDE) cycles at ambient and initial engine temperatures ranging from -20 °C to +23 °C. In total, 21 cases are considered, consisting of eight different ambient temperatures and five distinct driving cycles. Each case consists of a sequence of 2500
Mangipudi, Manoj, Denev, Jordan A., Bockhorn, Henning, Trimis, Dimosthenis, Koch, Thomas, Debus, Charlotte, Götz, Markus, Zirwes, Thorsten, Hagen, Fabian P., Tofighian, Hesam, Wagner, Uwe, Braun, Samuel, Lanzer, Theodor, Knapp, Sebastian M.
Technical Paper
Method for externally controlled availability of lubricating oil in internal combustion engines.2025-01-0302To be published on 07/02/2025
Reduced emissions in internal combustion engines (ICE) are a key component in reaching green-house-gas and pollutive emissions regulations. With increased effort, clean and efficient burning combustion cycles are being developed. With the need of even more efficient engines the friction of ICE engines plays an increasing role in engine efficiency. Also, ingress of lubricating oil into the combustion chamber is a source of particle emissions. Increased optimization to reduce parasitic drag in the piston assembly such as reduced ring pre-tension ore thinner grade oils further increase oil ingress into the combustion chamber with the result of increased particle emissions. The transport mechanisms of oil ingress into the combustion chamber therefore the topic of current research. Specially developed research engines with a vertical optical window have big potentials to visualize phenomena of the oil behavior inside the piston assembly in internal combustion engines. Therefore, these
Stark, Michael, Fellner, Felix, Härtl, Martin, Jaensch, Malte
Technical Paper
Optimized Cabin Heating Strategy for Battery Electric CEP Vehicles2025-01-0263To be published on 07/02/2025
Electromobility is gaining significance in the CEP (Courier, Express, and Parcel) sector, as parcel service providers increasingly rely on zero-emission vehicles to improve their CO2 balance. A general disadvantage of electric vehicles is the reduced range under cold operating conditions due to the higher energy demand for cabin heating. Another CEP-specific effect which affects the energy demand and thermal cabin comfort is the frequent door opening during the parcel delivery. Additionally, the vehicle cabin cools down during the driver’s absence because the cabin heating is turned off. Despite an acceptable level of thermal comfort must be maintained during the driving phases. This paper proposes an optimization-based strategy for the cabin heating of battery electric CEP vehicles. The objective is to maximize the cabin temperature during the driving phases compared to a baseline heating strategy while maintaining a desired energy consumption. For this purpose, a nonlinear model
Rehm, Dominik, Krost, Jonathan, Meywerk, Martin, Czarnetzki, Walter
Technical Paper
Application of Sustainable Aviation Fuels in CI Aviation Engines: In-Flight Investigations2025-01-0317To be published on 07/02/2025
To achieve a significant reduction in net CO₂ emissions in the aviation sector, sustainable aviation fuels (SAFs) are considered a key factor. Current research efforts are therefore focused on SAFs, which exhibit properties that differ from conventional kerosene, particularly in aspects critical to compression-ignition (CI) engines, such as cetane number, evaporation behavior or lubricity. These differences necessitate dedicated investigations to assess their suitability and performance in such engines. However, real operating conditions — such as intake air- and exhaust- pressure levels during flight — cannot be fully replicated on standard engine test benches. For this reason, real flight experiments were conducted to address these limitations. Notably, this work marks the first instance of in-flight testing of SAFs in CI aviation engines, constituting a significant milestone in this research area. In the course of these investigations, ASTM D7566 Annex A2-compliant HEFA
Kleissner, Florian, Reitmayr, Christian, Hofmann, Peter
Technical Paper
Optimization of Metallic Substrate by 1D simulations to fulfill High Power Cold Start Conditions2025-01-0308To be published on 07/02/2025
The future of the internal combustion engine is strictly related to his capability to have Life Cycle Emission comparable to the pure Battery Electric Vehicles. To achieve this goal, it will be necessary not only to have carbon free fuels but also to increase the hybridization of the powertrain in order to have lower fuel consumption. On the other hand, it will be necessary to reduce to almost zero any further emissions of pollutants. For this reason, highly sophisticated exhaust aftertreatment must be developed. One particular use case is the so-called High-Power Cold Start. This can occur for the Plug-In Hybrid Electric Vehicles when the transition from pure electric drive to ICE assisted drive happens during high load request, for example an acceleration on the freeway ramp. This use case has been evaluated by CARB and in many other works. Nevertheless, in this particular paper, the Authors would like to investigate which Metallic Substrate Technology fits better during a HPCS. This
Montenegro, Gianluca, Onorati, Angelo, Della Torre, Augusto, Marinoni, Andrea, Pace, Lorenzo, Konieczny, Katrin, Laurell, Mats, Klövmark, Henrik
Technical Paper
Effect of Gasoline Component on Fuel Economy of WLTC Drive with EGR and Lean Combustion2025-01-0305To be published on 07/02/2025
It is becoming increasingly clear that research into alternative fuels, including drop-in fuels, is essential for the continued survival of the internal combustion engine. In this study, the authors have evaluated olefinic and oxygenated fuels as drop-in fuels using a single-cylinder engine and considering fuel characteristic parameters. The authors have assessed thermal efficiency by adding the EGR or air from 0 to the maximum value that allows stable combustion. Next, we attempted to predict fuel efficiency for four types of passenger cars (Japanese small K-car N/A, K-car T/C, Series-HV, and Power-split-HV) by changing the fuels. We created a model in OpenModelica to estimate fuel efficiency during WLTC driving. The results indicated that fuel economy could potentially be improved by adding an olefin fuel that burns stably even with a large amount of EGR or air and an oxygen fuel whose octane number increases. It was observed that the fuel economy improvement rate was particularly
Moriyoshi, Yasuo, Xu, Fuguo, Wang, Zhiyuan, Tanaka, Kotaro, Kuboyama, Tatsuya
Technical Paper
Methodology for Fast-Running, Time-Resolved Simulation of Non-Exhaust Particle Emissions from Brake Wear Abrasion2025-01-0275To be published on 07/02/2025
Non-exhaust particle emissions, particularly those generated by brake wear, are a significant source of fine particulate matter in urban environments. These emissions contribute to air pollution and pose serious health risks, particularly in densely populated areas. While vehicle exhaust emissions have been extensively studied and regulated, the contribution of non-exhaust sources, including brake wear, remains a critical factor in air quality management. This paper presents a novel methodology for fast-running, time-resolved simulation of non-exhaust particle emissions, specifically those from brake wear abrasion. A 3D CFD model computes the turbulent flow field around the disc brake. The resulting information on the convective air cooling is applied as boundary conditions on a 3D thermal model. This thermal simulation setup is compared and verified with experimental data from literature. The 3D numerical models produce data and boundary conditions for an efficient 1D numerical
Herkenrath, Ferris, Lückerath, Moritz, Günther, Marco, Pischinger, Stefan
Technical Paper
Investigating lubricants base oils reactivity in ammonia/hydrogen engines via accelerated aging2025-01-0240To be published on 06/16/2025
As a carbon-free molecule, ammonia is more and more considered as a relevant fuel for long distance and off-road applications. However, this gas has different combustion characteristics compared to conventional fuels, challenging the suitability of lubricants to such engines. In this work, the evolution of lubricants under conditions mimicking ammonia combustion was assessed. Mineral and polyester lubricant base oils were exposed to oxygen, nitrogen oxides, and ammonia in a pressurized reactor under stirring. Oil aliquots were sampled at regular intervals, and characterized using Fourier Transform Infrared Spectroscopy (FTIR), viscosity and total oxygen and nitrogen contents measurements. Exposure to air containing nitrogen oxides resulted in quicker accumulation of oxidation products compared to neat air, for both the mineral and complex polyester base oil. Besides, exposure to gaseous ammonia in air resulted in a slower oxidation rate for both oils, compared to neat air. A global
Doncoeur, Carole, Giarracca, Lucia, Cologon, Perrine, Rousselle, Christine
Technical Paper
Commercial Vehicle’s Exhaust Front Pipe Reliability Improvement through Virtual Simulation and Experimental Validation2025-01-0209To be published on 06/16/2025
The exhaust front pipe is a critical structural component in commercial vehicles, ensuring the leak-proof flow of exhaust gases into the exhaust after-treatment system while withstanding engine and frame vibrations. To isolate these vibrations, the front pipe is equipped with a flex connector capable of enduring various displacements at frequencies between 8-25 Hz. The position of the flex connector relative to the engine crank axis significantly impacts its structural reliability over its service life. This paper compares the existing design, which features a horizontally positioned flex connector, with a modified design that positions the flex connector vertically and changes the material from SS-304 to SS-321. Finite element analysis was conducted using Nastran software. The fatigue life of the existing flex connector design is approximately 1015 cycles. In contrast, the improved design demonstrates a fatigue life of 1727 cycles, representing a 70% increase in durability compared to
Chandel, Kushal, Paroche, Sonu, NAMDEV, AKHILESH, Jain, Shailendra, Patil, Keyur
Technical Paper
Techno-Economic Analysis of an Integrated E-Methanol Production Plant Utilizing First and Second Generation Biomass Resources2025-01-0182To be published on 06/16/2025
Building upon foundational research utilizing Aspen Plus modeling for e-methanol production from sugar cane and sugar beet biomass, this study advances by incorporating a comprehensive techno-economic assessment (TEA) of an integrated e-methanol production system. The established integrated system converts biomass into ethanol through fermentation and synthesizes e-methanol using both captured CO2 and syngas derived from biomass residue gasification. The approach optimizes dual utilization of CO2 and biomass thereby fostering a circular carbon economy. The TEA quantifies capital expenditures (CAPEX), operational expenditures (OPEX), and levelized costs of energy (LCOE), providing a detailed economic analysis of the potential for commercializing e-methanol. Additionally, a sensitivity analysis is conducted to evaluate the impact of variable factors such as feedstock prices, process yields, and energy costs on the economic outcomes. This sensitivity analysis is crucial for understanding
Fernandes, Renston Jake, Shakeel, Mohammad Raghib, Nguyen, Ducduy, Im, Hong G., Turner, James W.G.
Technical Paper
Overview of Indian Government Policies, Regulations and Automotive Company Strategies toward Net-zero Emissions2025-01-0184To be published on 06/16/2025
The automotive sector in India is undergoing a transformation, driven by government policies and regulations aimed at achieving net-zero carbon emissions. In alignment with global climate goals, the Indian government has set ambitious targets to reduce greenhouse gas emissions, with a focus on promoting Electric Vehicles (EVs) and Hydrogen Fuel Cell Vehicles (FCVs). Initiatives like the Faster Adoption and Manufacturing of Hybrid and Electric Vehicles (FAME) Scheme, along with tax incentives, subsidies, and charging infrastructure development, are designed to accelerate the adoption of cleaner vehicles. The introduction of stricter emission standards and the National Electric Mobility Mission Plan (NEMMP) further underscores the push toward sustainable mobility. In response, Indian automotive companies are shifting strategies to align with these government directives. Major players are significantly increasing investments in EV technology, focusing on enhancing battery performance
Patil, NIKHIL, Saurabh, Saurabh, Gawhade, Ravikant, Bhardwaj, Rohit, Gadve, Dhananjay, Amancharla, Naga Chaithanya
Technical Paper
Effect of ignition condition and fuel octane number on knock intensity in a small 2-stroke engine2025-01-0211To be published on 06/16/2025
The internal combustion engines are widely used on automotive transportation for its high energy storage system efficiency and the economic benefits. The 4-stroke engine has dominated all other forms to date, because the Otto cycle is much simpler to comprehend. However, the significant benefits such as, less pumping work and friction, lighter construction of 2-stroke engine, helped with applications which appreciate the simplicity and power density as well as meet the emission regulations. The disadvantages of the 2-stroke engine mainly caused by the lack of sufficient scavenging process, which limited its trapping efficiency. Also, the overlap of the intake and exhaust phases results in charge short-circuiting, more fuel consumption and high unburned hydrocarbon emissions. For the reason above, it is difficult for 2-stroke engines to realize stoichiometric combustion and unable to use three-way catalyst to control emissions. The residual exhaust gas in the cylinder makes the spark
Liu, Jinru, Iijima, Akira, Yamazaki, Yoshiaki, Yokota, Takumi, Kato, Hayato, Otaki, Yusuke
Technical Paper
Comparison of spark and turbulent jet ignition in a fully ammonia-fueled engine2025-01-0201To be published on 06/16/2025
Ammonia (NH₃) is an emerging carbon-free fuel with the potential to decarbonize the energy sector. However, its widespread adoption is hindered by challenges like low flame speed, high ignition energy, and elevated emissions of nitrogen oxides (NOx) and unburnt NH₃. These limitations necessitate innovative combustion strategies for efficient and stable engine operation. This study investigates the potential of turbulent jet ignition (TJI) to overcome these challenges through the implementation of a pre-chamber, a small auxiliary chamber equipped with a spark plug to create hot, reactive jets that propagate into the main chamber, promoting rapid combustion from distributed ignition sites. In this work, TJI operation is compared to conventional spark ignition (SI) in a Cummins ISB6.7 engine retrofitted for 100% ammonia operation. Experiments were conducted at 1200 and 1800 RPM across varying loads (25%, 50%, 75%, and 100%) with equivalence ratio and spark timing sweeps. Combustion
Dhotre, Akash, Voris, Alex, Okey, Nathan, Kane, Seamus, Northrop, William
Technical Paper
Ultra low engine-out particle emissions from gas fuelled engines through lube oil formulation: evidence from an experimental campaign and machine learning based approach for data analysis2025-01-0249To be published on 06/16/2025
The transportation industry has undergone major changes in the past years, switching from traditional fossil fuels supply to alternative and cleaner ones. This is true especially in the field of heavy-duty (HD) engines, where Compressed Natural Gas is currently the most valid substitute of Diesel for off-road and transport applications. The upcoming stringent limits on sub-23 nm particles emissions will regard also gas fuelled engines; their compliance with future regulations requires great technological effort. The present work is addressed to the investigation of strategies to reduce particles emitted from HD gas engines. In particular, focus of the activity is the study of the potentiality offered by lubricant oils formulation in particle number (PN) emissions control. Indeed, particle emissions from gas engines come mainly from the combustion of lubricant oil leaking into the engine combustion chamber. An extensive experimental campaign on an HD SI engine with different lubricants
Guido, Chiara, Napolitano, Pierpaolo, Arpino, Alfonso, Cerbone, Daniele, Di Domenico, Davide, Beatrice, Carlo, Bozza, Fabio
Technical Paper
Combustion and emission characteristics of marine Ammonia-Diesel dual fuel single-cylinder engine with MP injector change2025-01-0235To be published on 06/16/2025
Recently, as regulations on greenhouse gas emissions due to global warming have tightened, there has been growing interest in engines that use environmentally friendly fuels. In this context, ammonia is gaining attention as a potential alternative to fossil fuels in the future. However, due to the unique fuel characteristics of ammonia compared to traditional fuels, research is being conducted on using diesel as an ammonia ignition source. In this study, combustion and exhaust characteristics were compared according to the characteristics of micro-pilot diesel injectors in the marine ammonia-diesel dual fuel single-cylinder engine. Various injectors with different hole numbers and sizes were examined (Injector A: more holes and larger size, Injector B: fewer holes and smaller size). To maintain a constant energy ratio between ammonia and diesel at a steady load, the injection duration was adjusted, and the MP injection timing varied in 5 CAD intervals to evaluate performance and
Jang, Ilpum, Park, Cheolwoong, Kim, Minki, Park, Chansoo, Kim, Yongrae, Park, Gyeongtae, Lee, Jeongwoo
Technical Paper
Analysis of Combustion Characteristics of a Small 2-Stroke Opposed Piston Engine Using an Optically Accessible Engine and Numerical Analysis2025-01-0223To be published on 06/16/2025
As global warming becomes more serious, decarbonization of internal combustion engines, which emit a large amount of carbon dioxide, is being promoted. It is predicted that many vehicles will still be equipped with engines in 2035, and a variety of powertrains will be required in the future. Therefore, we focused on the opposed-piston engine as an internal combustion engine specialized for power generation applications. The opposed-piston engine is characterized by its light weight due to the absence of a cylinder head, low S/V ratio due to the ultra-long stroke, reduced cooling loss due to the long stroke, and reduced vibration due to the offsetting of the reciprocating inertial forces of the left and right pistons. We believe that the engine for power generation can achieve the required high efficiency operation and vibration reduction. Therefore, in this study, combustion analysis of a two-stroke opposed-piston engine with features of low vibration, high efficiency, and high output
Yamazaki, Yoshiaki, Iijima, Akira, Liu, Jinru, Otaki, Yusuke, Watanabe, Sou, Okawara, Ikumi
Technical Paper
A Study on the Effects of Combustion Duration on Engine Behavior, Emissions, and Residual Gas in a Propane-Fueled Spark-Ignition Engine under Varying Loads2025-01-0202To be published on 06/16/2025
This study examines the effects of combustion duration on combustion behavior, pollutant formation, and residual gas fraction (RGF) in a propane-fueled spark-ignition engine across different load regimes. Experiments were conducted on a twin-cylinder research engine equipped with a dynamometer, varying the combustion duration between 40 and 80 degrees. Engine performance, emissions, and RGF were analyzed at engine loads of 25%, 50%, and 100%. The findings demonstrate distinct trends in combustion dynamics, emissions, and RGF as combustion duration and engine load change. At lower loads (25% and 50%), RGF fluctuations remain moderate, with peak values at specific combustion durations. In contrast, at 100% load, RGF shows significant deviations, indicating complex interactions between combustion and load. Additionally, variations in effective release energy (ERE), brake mean effective pressure (BMEP), and brake specific fuel consumption (BSFC) were observed, with longer combustion
Quach, Nhu Y
Technical Paper
A Comprehensive Experimental Analysis of Ethanol 27% Fuel Blend in a Turbocharged Gasoline Direct Injection Engine2025-01-0245To be published on 06/16/2025
India is committed to achieving a 20% ethanol blend in petrol (E20) by 2025, as part of its national biofuels policy to reduce carbon emissions, enhance energy security, and support the agricultural economy. Building on E20's achievement in reducing GHG emissions, E27 fuel—which contains 27% ethanol in gasoline—is one of the means of advancing India's ethanol strategy and reducing dependency on fossil fuels. In line with the literature and the preliminary study, an experimental analysis utilizing fuel blends ranging from E10 to E40 was conducted. It was found that E27 provides the optimal balance of emissions reduction and performance without requiring engine modifications, complying with the government's aim to boost ethanol blending and cut carbon emissions by 2030. This study examines a turbocharged gasoline direct injection (TGDI) engine powered passenger car that was tested using E27 fuel for a mileage accumulation of 20,000 km under real-world driving conditions. This evaluation
D R, Vigneshwar, Bhakthavachalu, Vijayabaskar, Muralidharan, M.
Technical Paper
An Experimental Study on Aqueous Ammonia and Diesel Dual-Fuel Combustion with Ignition Improving Additives in a Compression Ignition Engine2025-01-0231To be published on 06/16/2025
Ammonia is a potential vector of renewably produced hydrogen for combustion systems and decarbonisation of transport. However, anhydrous ammonia remains dangerous and difficult to handle due to its volatility and toxicity. Therefore, a water-based solution of ammonium hydroxide (NH4OH) was proposed to investigate the potential use as a fuel in a compression-ignition engine. Ammonium hydroxide, also referred to as aqueous ammonia, is liquid phase under atmospheric conditions; therefore, the storage of such a fuel does not require high pressure. Previous work has established that ammonium hydroxide solution could contribute to energy release during co-combustion with fossil diesel. However, the presence of water reduced combustion stability and limited the extent to which aqueous ammonia could displace diesel. In addition, the characteristics of pollutant emissions of burning such a fuel remained less understood. This study therefore explores the potential of ignition improving additives
Han, Yanlin, Hellier, Paul, Ladommatos, Nicos
Technical Paper
Research on Combustion Characteristics of Flash-Boiling Spray in Cylinders Based on Machine Learning Methods2025-01-0205To be published on 06/16/2025
With the increasing number of vehicles in operation, exhaust emissions from engines have exerted negative impacts on ecological environments, prompting researchers to actively pursue cleaner and more efficient in-cylinder combustion strategies. Flash-boiling spray technology, capable of generating superior fuel atomization under relatively low injection pressures, has emerged as a promising approach for achieving performance breakthroughs in gasoline direct injection (GDI) engines. While current research primarily focuses on morphological characterization and mechanistic analysis of flashboiling spray, there remains insufficient understanding of flame development characteristics under flash boiling spray conditions within engine cylinders. This study systematically investigates the combustion characteristics of TPRF and PRF fuels under both subcooled and flash-boiling spray conditions through the integration of image processing and machine learning methodologies. Experimental
Zhang, Weixuan, Shahbaz, Muhammad, Cui, Mingli, Li, Xuesong, Xu, Min
Technical Paper
Effects of Double Injection Strategy in a Diesel-Ammonia Dual-Fuel Engine2025-01-0206To be published on 06/16/2025
This study investigates the application of a double injection strategy in a single-cylinder marine diesel-ammonia dual-fuel engine retrofitted for experimental analysis. Diesel micro-pilot (MP) injection was used to ignite ammonia combustion, with diesel and ammonia injected separately into the cylinder through dedicated injectors. The first MP injection timing was fixed at -20 CAD before ammonia injection timing, and both early and late double MP injection strategies were implemented to evaluate their effects on ammonia combustion, engine performance, and exhaust emissions. Under all conditions, the ammonia injection timing remained constant. Early double injection strategies, with the second MP injection occurring before the first, enhanced premixed diesel combustion by raising in-cylinder temperature and pressure. However, this early heat release was ineffective for ammonia evaporation and combustion due to poor timing alignment. In contrast, late double injection strategies, with
Park, Chansoo, jang, Ilpum, Park, Cheolwoong, Kim, Minki, Park, Gyeongtae
Technical Paper
Comparison of HRD and Petro Diesel in Industrial Engine Applications2025-01-0243To be published on 06/16/2025
Renewable fuels are seen as a key enabler on the path to a lower carbon future. A low greenhouse gas fuel of particular interest is hydrotreated renewable diesel (HRD), also known as hydrotreated vegetable oil (HVO). HRD is of interest because it is a drop-in replacement to existing petroleum fuels used in diesel engines. An experimental investigation was undertaken to evaluate combustion characteristics of HRD versus a standard petroleum diesel. The work was carried out using a 2.5-liter fully instrumented single-cylinder research engine. This engine was chosen because it provides a very precise view of the difference in combustion and emissions of the fuels. Results represent the difference in combustion characteristics of the fuels, rather than potential differences in engine performance seen in a production engine, as each particular engine model will react a bit differently to the changes in combustion. The engine was operated according to three ISO 8178-4 test cycles: C1, D2, and
Bardell, Michael, Abi-Akar, Hind, Seiler, Patrick, Nash, Brady, McMahon, Donna, Ioannou, Marios
Technical Paper
numerical investigation into the combustion and emission characteristics of ammonia direct injection mechanism2025-01-0241To be published on 06/16/2025
Ammonia is an attractive option because of its relatively low greenhouse gas (GHG) emissions, high energy density, competitive cost, and ubiquitous infrastructure for manufacturing, storage, and distribution. In this work, the optimum combustion characteristics are investigated to propose an efficient ammonia engine for future investigation. The effects of ammonia addition on diesel combustion characteristics were numerically investigated in a CI engine. The investigation was conducted by structured 3D CFD modeling to analyze the combustion characteristics. The validation of the boundary condition was compared to the designed experimental ammonia engine. The direct injection timing of 10o-50oBTDC and injection pressure 300-800 bar was proposed to identify the optimum autoignition characteristics. The equivalence ratios 1, 0.75, 0.5, and 0.25 were used in order to analyze the high cetane number characteristics and the air-fuel ratio.
setiawan, ardhika, Lim, Ocktaeck
Technical Paper
Thermal efficiency improvement and emission reduction of methanol spark ignition engine using lean-burn strategy2025-01-0224To be published on 06/16/2025
Methanol is a promising fuel for achieving carbon neutrality in the transportation sector, particularly for internal combustion engine vehicles. With its high-Octane number, methanol enables higher thermal efficiency compared to gasoline engines. Additionally, its wide flammability range allows stable engine operation under lean burn conditions at low to mid-load levels. In this study, experiments were conducted on a single-cylinder engine to examine the combustion and emission characteristics under varying excess air ratios and injection timings. The results showed that the highest thermal efficiency was achieved at the highest excess air ratio, despite the lowest combustion efficiency and the longest burn duration. This outcome highlights that a larger air mass reduces heat loss and pumping loss. Furthermore, NOx emissions decreased due to the reduction in in-cylinder temperatures. However, HC emissions increased as a result of the decline in combustion efficiency
Lee, Seungwon, Kim, Hyunsoo, Hwang, Joonsik, Bae, Choongsik
Technical Paper
Impact of reduced catalytic activity on passive regeneration of catalyzed diesel particulate filters2025-01-0185To be published on 06/16/2025
Oxidation catalysts can greatly improve the regeneration efficiency of diesel particulate filters (DPF) by providing sufficient levels of NO2 for low-temperature soot oxidation. As for other automotive catalysts, catalyzed DPFs (CDPFs) are subject to aging effects, resulting in decreased performance of the NO oxidation reaction. The life span of CDPFs generally only considers the elevated back pressure as a consequence of the accumulation of ash. However, with reduced catalytic activity and impaired functionality of the regeneration process there is a risk of premature replacement of the CDPF or accumulation of soot above critical levels. In this study, a new exhaust aftertreatment system has been developed to accommodate sub-scale catalysts and DPFs for testing with full-size heavy-duty engines. The modified exhaust aftertreatment system was used together with a rig for accelerated soot and ash loading to assess the impact of CDPF aging on regeneration performance under real
af Ugglas, Samuel, Finker, Pascal, Ersson, Anders, Yao, Dawei, Pettersson, Lars J., Kusar, Henrik
Technical Paper
Optimization of the lubricating oil composition to reduce emissions from hydrogen engines2025-01-0212To be published on 06/16/2025
The decarbonization of the transport sector has become a priority for governmental authorities and industrial stakeholders alike, driving regulatory measures and innovation in powertrain technologies. Among the innovative solutions, hydrogen combustion engines have gained significant attention due to their customization to diverse applications, including heavy-duty vehicles, passenger cars, generators, and even two- and three-wheelers. Hydrogen combustion, characterized by high ignitability, rapid flame speed, soot-free operation, and water as a combustion by-product, introduces distinct challenges for engine lubrication. These unique characteristics require the development and adaptation of lubricant formulations to ensure optimal engine performance and durability. Specifically, tailored lubricants play a vital role in addressing four key challenges: pre-ignition, particulate emissions, water contamination, and wear protection. This study investigates the impact of crucial formulation
Gohl, Marcus, Wulff, Robert, Scholl, Peter, Günthner, Michael, Jung, Philipp Emanuel, Chapelot, Pierre
Technical Paper
Evaluating the Impact of Displacing Injected Gasoline with Aspirated Ammonia in a Direct Injection Spark Ignition Engine2025-01-0226To be published on 06/16/2025
Replacing fossil fuels with renewable ammonia could provide a crucial step towards the decarbonisation of transport sectors. However, many challenges remain in utilising ammonia within combustion systems: the volumetric energy density of ammonia is significantly lower than that of gasoline, exposure to ammonia (including ammonia slip) can be detrimental to human health, and the production of emissions, including unregulated emissions (such as N2O), from ammonia combustion can be catastrophic for the environment if not treated appropriately. Therefore, there is a need to determine the efficacy of ammonia as a fuel for internal combustion engines and the impact on the efficiency of energy release and the resulting exhaust emissions. A modern spark ignition engine was modified such that ammonia was aspirated through the engine intake air to incrementally displace engine gasoline and maintain a constant work output. It was found that displacing the fuel energy supplied by direct injected
Sivaranjitham, Annaniya Mitchell, Hellier, Paul, Ladommatos, Nicos, Millington, Paul, Alcove Clave, Silvia
Technical Paper
Catalyzing the Hydrogen Economy: Designing Low-Cost Refueling Modules for India's Mobility Revolution2025-01-0187To be published on 06/16/2025
The likely depletion of fossil fuel reserves in the next fifty years and growing environmental concerns caused by petroleum fuel-based vehicles highlight the urgent need for sustainable alternatives. India, a developing country, requires a significant amount of energy to sustain its growth, most of which is imported. Hydrogen is one of the cleanest fuels and offers sustainable pathways to a low-carbon future. The government of India has already launched a Green Hydrogen mission and has set up a very ambitious target for 2030. However, the absence of adequate refueling infrastructure is a significant blockade to India's widespread adoption of hydrogen-powered vehicles. The mobile hydrogen refueling station (MHRS) is a flexible system that enables lower initial capital costs than fixed hydrogen refueling stations and allows for the gradual build-up of hydrogen mobility fleets. Such a system could be very useful in India, and it integrates advanced safety features, including hydrogen leak
Mathur, Animesh, Nayak, Ajay, Kumar, Naveen
Technical Paper
Understanding how blending different ratios of renewable fuels with diesel impacts the toxicity of exhaust particulates to human health.2025-01-0207To be published on 06/16/2025
The urgent need to decarbonise transport has increased the utilisation of renewable fuels with current hydrocarbons. Heavy duty vehicle electrification solutions are yet to be realised and therefore the reliance on diesel engines may still be present for decades to come. Currently, the diesel supplied to fuel stations across the UK is a 7% blended biodiesel, whilst in South Korea a 5% blend is utilised. Biodiesel is produced from renewable sources for example; crops, waste residue and oils or biomass. Particulates from diesel combustion are known to be toxic, due to the presence of polyaromatic hydrocarbons (PAHs) however there is very limited understanding of blending oxygenated fuels on the toxicity of the particulates produced. PAHs are aromatic structures that can be metabolised into chemicals which can disrupt DNA replication and potentially influence cancer mechanisms if inhaled in high quantities. Soyabean methyl-ester (SME) was blended at lower ratios, e.g., 5%, 10%, 15% and
Hailwood, Emma, Hellier, Paul, Ladommatos, Nicos, Leonard, Martin
Technical Paper
Development of Simple Models for Performance Estimation of an Ammonia Fueled Spark Ignition Engine2025-01-0238To be published on 06/16/2025
Achieving a carbon neutral society, eliminating greenhouse gas emissions is one of the most important issues. Ammonia is expected as a carbon free energy source. However, the laminar burning velocity of ammonia is much slower than hydrocarbons. Then, it is common to reform a portion of ammonia and use the ammonia/hydrogen mixture as a fuel. In this research, the operating characteristics of spark-ignition engine fueled with ammonia reformed gas is investigated and construct model estimating engine performance. A four-stroke single cylinder spark-ignition engine with a stroke volume of 212 cm3 is used. Total equivalence ratio is kept at unity and ammonia equivalence ratio is changed. Also, ammonia reformed gas is simulated as follows: ammonia and hydrogen are supplied from high pressure cylinders and injected by using automobile gaseous fuel injectors. Nitrogen is supplied from high pressure cylinder and supplied 1/3 of the molar ratio to hydrogen by a mass flow controller. The test
Ichikawa, Aya, Ogura, Yuto, Yanaoka, Kazuki, Gonzalez Palencia, Juan, Kambara, Shinji, Araki, Mikiya
Technical Paper
Evaluation of Several Jet Fuels under Compression-ignition Operation on Thermal Efficiency, NOx, Particulate Matter, and Particle Size Distribution2025-01-0244To be published on 06/16/2025
Alternative fuels such as Fischer-Tropsch Synthesized Paraffinic Kerosene (FT-SPK) and Catalytic Hydrothermal Conversion Jet (CHCJ) are among those important sustainable aviation fuels (SAFs) for future transportation. However, these alternative fuels often vary in their fuel characteristics, which depend on feedstock and fuel production processes. Therefore, a detailed analysis of combustion, emissions, and efficiency of these alternative fuels must be performed under controlled experiments to understand the impact of fuel properties and operating conditions. Using a single-cylinder research engine (SCRE), extensive operating conditions were performed to realize any difference in performance that can be fundamentally understood by fuel properties (e.g., cetane number, heat of combustion, and density) of these fuels in comparison with Jet-A. The experimental setup includes high-speed data acquisition for combustion analysis and gaseous and solid emissions benches for nitrogen oxides
Cung, Khanh, Miganakallu Narasimhamurthy, Niranjan, Khalek, Imad, Hansen, Greg
Technical Paper
Development of After-treatment Systems and Control Strategy for a Hybrid-dedicated Homogeneous Lean Burn Engine2025-01-0217To be published on 06/16/2025
Lean-burn gasoline engines can improve fuel economy thanks to the higher specific heat ratio of the mixture and the reduced cooling loss during the combustion process. In addition, when combined with hybrid technology, the technology can achieve more synergies by overcoming obstacles such as limited operating conditions. However, the challenge of this technology is to reduce exhaust emissions to a level suggested by future stringent regulations. In lean-burn gasoline engines, nitric oxide (NOx) emissions are difficult to convert using conventional three-way catalysts (TWCs). Therefore, developing an effective NOx after-treatment system has been a key technology in the development of lean-burn engines. In addition, hydrocarbon (HC) emissions are also challenging because they increase under lean combustion conditions, while the lower exhaust temperature under lean conditions makes them hard to oxidize. Therefore, a catalyst technology capable of effectively converting HC, even at a low
Oh, Heechang, Lee, Jonghyeok, Sim, kiseon, Lim, SeungSoo, Park, Jongil, Park, Minkyu, Kang, Hyunjin, Han, Donghee, Lee, Kwiyeon, Song, Jinwoo
Technical Paper
Life Cycle Assessment of Hydrogen Production via Steam Methane Reforming: Comparative Analysis of Steam and Electricity as Co-Products2025-01-0181To be published on 06/16/2025
This research presents a numerical analysis of the environmental impacts associated with using hot steam as a co-product in hydrogen production through Steam Methane Reforming (SMR) of renewable gas sources. As hydrogen production technology advances rapidly, reducing emissions and addressing environmental concerns, particularly greenhouse gas (GHG) emissions, have become essential. This study examines the SMR process with a focus on the environmental effects of utilizing hot steam as a co-product for electricity generation or facility heating. The analysis evaluates renewable feedstocks, including landfill gas, animal waste, food waste, and wastewater sludge, to determine their viability for sustainable hydrogen production. Key pollutants, such as carbon monoxide and nitrogen oxides, along with GHGs, are assessed to identify the most environmentally advantageous feedstock options. This work aims to provide insights promote sustainable hydrogen production practices.
Rosyadi, Ahmad Adib, Lim, Ocktaeck
Technical Paper
A Comparative Assessment of Port Fuel Injection and Direct Injection of Hydrogen in Internal Combustion Engines: Performance, Efficiency, and Emissions2025-01-0239To be published on 06/16/2025
With the transition toward low-carbon fuels-based transportation systems, hydrogen is becoming increasingly promising as a sustainable internal combustion engine (ICE) fuel. There are two pathways for introducing hydrogen: Port Fuel Injection (PFI) and Direct Injection (DI) in an engine, which greatly affects performance, efficiency, and emissions. In the Port Fuel Injection (PFI); hydrogen is introduced into the intake manifold and mixed with air before reaching the combustion chamber. This approach is preferred due to its affordability, ease of use, and compatibility with current engine configurations. Because of PFI's more uniform air-fuel mixture, combustion is smoother, and NOx emissions are reduced. On the other hand, it raises the possibility of pre-ignition, particularly when engine loads are high, and a decrease in volumetric efficiency due to a reduction in the volume of intake air as hydrogen replaces it. Direct injection gives exact control over the timing and volume of
Ahirwar, Sachin, Kumar, Naveen
Technical Paper
Pass-by Noise Contribution Analysis of an Agricultural Tractor2025-01-0134To be published on 05/05/2025
There is an increasing effort to reduce noise pollution across different industries worldwide. From a transportation standpoint, pass-by regulations aim to achieve this and have been implementing increasingly stricter emissions limits. Testing according to these standards is a requirement for homologation but does little to help manufacturers understand why their vehicles may be failing to meet limits. Using a developed methodology such as Pass-by Source Path Contribution (SPC, also known as TPA) allows for identification of dominant contributors to the pass-by receivers along with corresponding acoustic source strengths. This approach is commonly used for passenger vehicles, but impractical for off-highway applications, where vehicles are often too large for most pass-by-suitable chassis dynamometers. A hybrid approach is thereby needed, where the same techniques and instrumentation used in the indoor test are applied to scenarios in an outdoor environment. This allows for
Freeman, Todd, Engels, Bret, Thuesen, Ben
Technical Paper
Experimental Analysis of Pressure Pulsation Noise Phenomenon in a CNG-Powered Passenger Vehicle2025-01-0112To be published on 05/05/2025
Compressed Natural Gas (CNG) engine has proved itself to be a worthy replacement for conventional fuels like gasoline & diesel in heavy commercial and passenger transport applications all over the world. Natural gas can be used to reduce carbon dioxide emissions while the global distribution of natural gas allows energy independence for regions with gas rather than oil reserves. In India, infrastructure development of CNG distribution and stringent emission regulations have increased the interest shown by Original Equipment Manufacturers (OEM) to concentrate towards development of CNG vehicles in every segment. From noise & vibration perspective, CNG powered vehicles are expected to maintain the same level of cabin refinement as their fossil fuel equivalents. However, one of the major challenges associated with CNG vehicles is the excitation due to additional components like CNG Pressure Regulator, Injector et al. The operational metallic / pulsation noises are generally higher as
Chatterjee, Joydeep, Ravindran, Mugundaram
Technical Paper
Tonal noise investigation of automotive HVAC systems : a hybrid method2025-01-0027To be published on 05/05/2025
There is no need to recall how the electrification trend of transport facilities has tightened the requirements around acoustic comfort. Within the automotive industry, these targets are more challenging for Heating, Ventilation and Air Conditioning systems for which passengers are in the foreground of noise emissions. The complexity of the requirements and specifications set by car manufacturers and suppliers stems from a dual aspect. First is quantitative based on the sound pressure level, whether it's the overall level or 1/3 octave band spectra. The second is purely subjective based on the perceived noise quality by stakeholders and final customers worldwide. During development phases, low frequency tone noises are frequently encountered on these systems which might induce discomfort to the passengers. The experimental investigations usually point to an aerodynamic origin, which prompted this research activity. The purpose of this work is to analyze and understand the mechanism of
Bennouna, Saad, Alaoui, Mohamed, Henner, Manuel
Technical Paper
Evaluation of Portable Emission Measurement Systems (PEMS) Accuracy by Simultaneous Measurement of PEMS and Laboratory-Based Analyzers *2024-32-011304/18/2025
With growing concern to protect the atmosphere, the stringency of vehicle emission regulations is increasing annually [1,2]. Notably, evaluations of real driving emissions (RDEs) using portable emission measurement systems (PEMS) have been mandated for light duty vehicles (LDVs) in regions, such as the EU, China, India, and Japan [3,4]. Additionally, RDEs have attracted attention in motorcycles and was investigated in the effect study of the environmental step Euro 5 [5]. However, some inherent problems remain with RDE measurements using the PEMS on motorcycles. Due to the smaller engine displacement and fewer cylinders associated with motorcycles, resulting in lower exhaust gas flow rates, the measurement accuracy of the PEMS may be lower than that of the LDVs. Furthermore, exhaust emissions can be affected by the additional weight of the PEMS when mounted on motorcycles. This study investigated the accuracy of the PEMS in measuring motorcycle emissions by simultaneously measuring
Matsuoka, Masahiro, Hirai, Hiroshi, Ito, Takayuki
Technical Paper
Enhancing Low Temperature Lean Combustion of CH4-H2 Blends through a Prechamber Equipped Engine2024-32-004404/18/2025
The use of hydrogen as a sustainable fuel in the short term is hampered by the impossibility of large scale use due low availability. In order to promote decarbonization, complementary solution for a smooth transition is to dilute it in a mixture with methane, in a current Port Fuel Injection (PFI) internal combustion engine (ICE). This can be done as a retrofit after limited structural modifications, such as the introduction of a passive prechamber. Such a solution allows a reduction of the carbon footprint of traditional ICEs through more efficient combustion (both the prechamber technology and the hydrogen fuel properties promote an increase in combustion speed) and a reduced carbon content in the fuel. The present research activity has been carried out through numerical investigation based on three-dimensional CFD analyses to simulate the behavior of a natural gas engine fueled with CH4-H2 blends. The combustion mechanism for the fuel blend was validated against measurements of the
Balduzzi, Francesco, Ferrara, Giovanni, Di Iorio, Silvana, Sementa, Paolo
Technical Paper
Effects of CO 2 Concentration on Combustion Characteristics of Compressed Biomethane Gas2024-32-011104/18/2025
One way to decarbonize spark-ignition (SI) engines is to use alternative fuels to improve thermal efficiency. Compressed biomethane gas (CBG), mainly composed of methane and carbon dioxide produced from food waste, has attracted attention as an alternative fuel, but its carbon dioxide content is indeterminate. This study investigates the effects of carbon dioxide content on engine performance (thermal efficiency, etc.), emission characteristics, and turbulent burning velocity using a CBG surrogate fuel mixed with methane and carbon dioxide. A single-cylinder SI engine is used as the test engine, and experiments are conducted under different load conditions with a constant crank angle of 50% mass fraction burned (CA50). Engine performance is analyzed based on heat balance from in-cylinder pressure analysis. Emission characteristics are measured using an emission gas analyzer. Using the boundary conditions obtained from the experiments, parameters such as unstretched laminar burning
Kobayashi, Takuma, Shimizu, Taketoshi, Yoshimura, Kei, Sok, Ratnak, Kusaka, Jin
Technical Paper
Development of NOx Storage Catalyst and Investigation of Deterioration Mechanism for Small Powertrains2024-32-009704/18/2025
In response to the evolving landscape of exhaust gas regulations for small powertrains, reducing NOx emission is increasingly important. This study deeply investigated the feasibility of a NOx storage catalyst (NSC) containing cerium oxide (CeO2) and barium oxide (BaO) for reducing NOx emission. The key functions, NOx storage and reduction performances were evaluated, and deterioration mechanisms were explored through performance evaluations and physical property analyses. The findings revealed a strong correlation between the size of CeO2 crystals and NOx storage performance at low temperature, such as those encountered during city driving conditions. Conversely, at high temperature, such as those during highway driving conditions, NOx storage performance correlated well with sulfur deposition, suggesting that the formation of barium sulfate (BaSO4) contributes to the deactivation. This experiment also showed a strong correlation between NOx reduction performance and BaSO4 formation
Nakano, Fumiya, Koito, Yusuke
Technical Paper
Experimental Study of Port Water Injection System on Single Cylinder Diesel Engine Performance and Exhaust Emission2024-32-002504/18/2025
Vehicle emission standards have become more and more stringent and have driven the development of advanced engine design with low-cost emission control technologies. For small diesel engine which is used in three-wheel (3W) passenger and load carrying vehicles, it was major task to improve lower engine rpm torque and performance to comply with stringent exhaust emissions standard as well, especially for Oxides of Nitrogen (NOx) and Particulate Matter (PM) emissions. Bharat Stage (BS) VI emission standards for three-wheel vehicles was implemented from April 2020 onwards in India. Water injection technology has proven advantageous for low-cost solution with Mechanical fuel injection system on small diesel engines, Intake port water injection is the easiest method to introduce water to engine cylinder, which calls for minimal modification of existing engine structure. In the present study 435cc naturally aspirated DI Diesel engine used for three-wheel vehicle was explored by adding water
Syed, Kaleemuddin, Chaudhari, Sandip, Khairnar, Girish, Katariya, Rahul, Jagtap, Pranjal, Bhoite, Vikram
Technical Paper
Real-Time Control of Hydrogen Injection in a PFI Internal Combustion Engine based on an Online Physics-Based Model for Estimating Trapped Air and EGR2024-32-010304/18/2025
The use of hydrogen in port fuel injection (PFI) engines faces challenges related to abnormal combustions that must be addressed, especially in transient operation. The in-cylinder air-to-fuel ratio and the amount of trapped exhaust gas have a significant impact on the probability of abnormal combustion as well as NOx emissions, and should be real-time monitored in hydrogen engines. Thus, the real-time estimation of the composition and thermodynamic state of the trapped gas mixture is crucial during transient operations, although highly challenging. This study proposes an on-line real-time physics-based MIMO (Multi-Input-Multi-Output) model to accurately estimate the amount of trapped air and exhaust gas in the cylinder at the intake valve closing (IVC) event, based on the instantaneous in-cylinder pressure measurement. With proper estimation accuracy, the injector can be controlled to correctly provide the amount of fuel necessary to achieve the target air-to-fuel ratio (AFR) and
Galli, Claudio, Ciampolini, Marco, Drovandi, Lorenzo, Romani, Luca, Balduzzi, Francesco, Ferrara, Giovanni, Vichi, Giovanni, Minamino, Ryota
Technical Paper
Numerical Studies on the Relation between the Multiple Auto-Ignition and Pressure Wave in the Premixed Charge2024-32-007904/18/2025
The relation between the multiple auto-ignition in the premixed charge with fuel concentration distribution and associated pressure wave are numerically investigated. This study assumes that the auto-ignition phenomenon in the end-gas of PCCI combustion, a next-generation combustion method which is expected to achieve both low fuel consumption and low emissions at a high level. Detailed numerical analysis considering the elementary chemical reactions of the compressible reacting fluid flow described in the one-dimensional coordinate system with high spatial and time resolution was performed to clarify the detailed phenomena of the onset of the multiple auto-ignition and the pressure wave propagation in the gas.
Iizumi, Kota, Yoshida, Kenji
Technical Paper
Development of CO 2 Emission Reduction Technology for Sport Motorcycles2024-32-009604/18/2025
With growing global concern about climate change, the challenge is to achieve carbon neutrality (CN) in motorcycles (MCs) as well, and various approaches are needed to achieve CN. For powertrains using internal combustion engines (ICEs), CN can be achieved by adopting CN fuels such as e-fuel and biofuel, but considering cost and supply, it is important to develop CO2 reduction technologies for ICEs. Compared with 4-wheel vehicles, MCs are required to be powerful, lightweight, compact and capable of travelling long distances, the CO2 reduction technologies that can be adopted tend to be a trade-off between dynamic performance and CO2 reduction, and a challenge is to achieve a high level of both requirements. We decided to focus on middle-class sports MCs, which require particularly high dynamic performance, and to develop CO2 reduction technologies. As a technology development target, CO2 emissions were set at 65 g/km in the worldwide-harmonized motorcycle test cycle (WMTC) class 3-2
Makita, Naoki, Torigoshi, Masaki, Takahashi, Toshihiko, Takase, Hiroki
Technical Paper
Experimental Study on Thermo-Catalytic Ammonia Decomposition into Hydrogen2024-32-011804/18/2025
In order to rapidly achieve the goal of global net-zero carbon emissions, ammonia (NH3) has been deemed as a potential alternative fuel, and reforming partial ammonia to hydrogen using engine exhaust waste heat is a promising technology which can improve the combustion performance and reduce the emission of ammonia-fueled engines. However, so far, comprehensive research on the correlation between the reforming characteristic for accessible engineering applications of ammonia catalytic decomposition is not abundant. Moreover, relevant experimental studies are far from sufficient. In this paper, we conducted the experiments of catalytic decomposition of ammonia into hydrogen based on a fixed-bed reactor with Ru-Al2O3 catalysts to study the effects of reaction temperature, gas hour space velocity (GHSV) and reaction pressure on the decomposition characteristics. At the same time, energy flow analysis was carried out to explore the effects of various reaction conditions on system
Li, Ze, Li, Tie, Chen, Run, Li, Shiyan, Zhou, Xinyi, Wang, Ning
Technical Paper
Coupled Analysis of First Principle Calculation and Chemical-Kinetics Simulation to Predict the Activity of Three Way Catalyst2024-32-000404/18/2025
This study proposes a technique to predict the catalytic activity of the CO-NO-O2 reaction using the first principle calculations without experiment. The proposed method consists of four steps. (1) Assuming the detailed chemical reactions based on the Langmuir-Hinshelwood mechanism. (2) Estimating the activation energy (Ea) for each detailed chemical reaction using first principle (e.g. Density Functional Theory: DFT) calculations. (3) Defining frequency factors (A) theoretically. (4) Inputting the estimated Ea and A values into simulation software for chemical-kinetics (e.g. exothermia suite) and running the simulation. The validity of the proposed method was evaluated by experiments. This study predicted the catalytic activities of Pt, Pd or Rh(111) surfaces. The predicted results qualitatively matched the experimental outcomes obtained from the Pt, Pd or Rh thin-film catalyst prepared by the “arc plasma method”.
Miura, Kazuya, Kusaba, Hiroki, Miyoshi, Tomoya, Yoshida, Hiroshi, Tsuchizaki, Hiroyuki, Machida, Masato
Technical Paper
Study on the Optimal Pre-Chamber Geometry for Active Pre-Chamber Gas Engines2024-32-002304/18/2025
In a pre-chamber engine, fuel in the main-chamber is ignited and combusted by the combustion gas injected from the pre-chamber. Therefore, further fuel dilution is possible and thermal efficiency can be also improved. However, adding a pre-chamber to an engine increases the number of design parameters which have a significant impact on the main combustion and the exhaust gas. Then, in this study, the optimum geometry of the pre-chamber in an active pre-chamber gas engine was investigated. The considered parameters were the volume of pre-chamber, the diameter of a nozzle hole, and the number of nozzle holes. 18 types of pre-chambers with different geometries were prepared. Using these pre-chambers, engine experiments under steady conditions were conducted while changing the conditions such as engine speeds, mean indicated pressure and air excess ratio. Based on the experimental data, neural network models were constructed that predict thermal efficiency, NOx and CO emissions from the
Yasuda, Kotaro, Yamasaki, Yudai, Sako, Takahiro, Takashima, Yoshitane, Suzuki, Kenta
Technical Paper
Evaluation and Visualization of Surfactant Effect on Single Emulsified Fuel Droplet for Diesel Engine2024-32-001004/18/2025
The emulsified fuel is mixed base fuel with water and stabilized by surfactant. The advantage of emulsified fuel is the improvement of spray and mixture formation by the secondary atomization. The secondary atomization means that the sprayed fuel droplets in cylinder would occur the atomization because of the difference of boiling points between base fuel and water. It is expected improving combustion efficiency and suppressing toxic emissions such as NOx and PM in small diesel engine [1]. The behavior of an emulsified fuel droplet in heating process has 3 types, Namely the micro-explosion, the puffing and only vaporizing without atomization. Their timing and behavior are influenced on the concentration of surfactant within an emulsified fuel droplet. However, it is difficult to determine the concentration. This paper focuses on the determination of the concentration by engineering evaluation. Our previous reports have reported that the evaluation for the atomization timing of an
Kurahashi, Yuta, Katsuki, Hiromu, Tanaka, Junya
Technical Paper
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